Dual vicinal functionalisation of heterocycles via an interrupted Pummerer coupling/[3,3]-sigmatropic rearrangement cascade† †Electronic supplementary information (ESI) available: Full experimental details, NMR spectra, CCDC numbers for X-ray structures. CCDC 1570504, 1570698. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc04723a

Enantioselective and diastereoselective azo-coupling/iminium-cyclizations: a unified strategy for the total syntheses of (–)-psychotriasine and (+)-pestalazine B† †Electronic supplementary information (ESI) available: Experimental, characterization data, X-ray structures of compound 15, and NMR spectra. CCDC 1040494. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00338e

Tsinghua-Peking Centre for Life Sciences, B Department of Pharmacology and Pharm Collaborative Innovation Center for Diagno Tsinghua University, Beijing 100084, China cn MOE Key Laboratory of Bioinformatics, Sch Beijing 100084, China. E-mail: [email protected] † Electronic supplementary informati characterization data, X-ray structures CCDC 1040494. For ESI and crystallogr format see DOI: 10.1039/c5s...

Synthesis of a novel polycyclic ring scaffold with antimitotic properties via a selective domino Heck–Suzuki reaction† †Electronic supplementary information (ESI) available: Full experimental details, 1H and 13C NMR spectra and X-ray crystallographic data for compound 4d. CCDC 936207. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02547d Click here for additional data file. Click here for additional data file.

Triple aryne–tetrazine reaction enabling rapid access to a new class of polyaromatic heterocycles† †Electronic supplementary information (ESI) available: Experimental protocols, characterization data, X-ray crystallographic data (CIF) and NMR spectra of all new compounds. CCDC 1400529. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01726b Click here for additional data file. Click here for additional data file.

Highly enantioselective access to diketopiperazines via cinchona alkaloid catalyzed Michael additions† †Electronic supplementary information (ESI) available: Experimental procedures, analytical data and NMR spectra, X-ray data. CCDC 977363, 977364, 977365 and 1017592. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03218g

Metathesis of a UV imido complex: a route to a terminal UV sulfide† †Electronic supplementary information (ESI) available: Full computational and experimental details, NMR spectra, and detailed X-ray crystallographic data in CIF format. CCDC 1535285–1535289. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc01111c Click here for additional data file. Click here for additional data file.

Institut des Sciences et Ingénierie Chim Lausanne (EPFL), 1015 Lausanne, Switzerla Université de Toulouse et CNRS INSA, UPS, Rangueil, 31077 Toulouse, France Department of Chemistry and Pharmacy, I University Erlangen-Nürnberg, Egerlandstra † Electronic supplementary information ( experimental details, NMR spectra, and CIF format. CCDC 1535285–1535289. Fo or other electronic format see DOI: 10....